Fergus Poynton, who joined the group in 2011 following his very successful spell as a Trinity College Scholar during his Bachelors Degree in Chemistry, defended his PhD Thesis (‘Spectroscopic Investigations into the Excited-state Processes and Reactivity of Ruthenium(II) Polypyridyl Complexes’) today.
The four year research project was conducted in collaboration with Trinity’s Prof John Kelly and Dr. Susan Quinn of UCD from which came many high impact publications including one which made the cover of Nature Chemistry. Examiners, including Trinity’s Prof. Rachel Evans and Prof. Andrée Kirsch – De Mesmaeker (Fanny) from the Université Libre de Bruxelles, joined the research group for a reception in the Trinity Biomedical Sciences Institute afterwards to celebrate.
Eoin McCarney, 2nd year PhD research chemist in the Gunnlaugsson group, had his first journal article published in Chemical Communications earlier this month. The work reported entails the formation and characterisation of a healable lanthanide luminescent metallogel from 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands. Co-authors include Gunnlaugsson group member Dr. Joe Byrne who supervised the initial stages of the project, crystallographers Dr. Brendan Twamley and Dr. Miguel Martínez-Calvo, physicists Gavin Ryan and Prof. Matthias Möbius for the rheological studies of the soft matter gel and Prof. Thorri Gunnlaugsson. DOI: 10.1039/C5CC03139G
A recent publication from the group reporting the first triple-clipped -catenane by lanthanide-directed synthetic methods was highlighted by College and Nature’s Research Highlights. Read College’s Press Release here:
Chemists from Trinity College Dublin have achieved a long-pursued molecular first by interlocking three molecules through a single point. Developing interlocked molecules is one of the greatest challenges facing researchers, and the Trinity chemists’ achievement represents the first time three molecules have been linked in a non-linear ‘chain-like’ form.
Interlocked molecules have major applications in nanoscience, as they can be used as molecular shuttles and switches, and because they can function as molecular motors, mimicking the action of many biological systems.
Molecules that are interlocked together are unique in that they are not connected by any chemical bonds, which give other compounds their individual, defined structures following chemical reactions. Instead, the interlocked molecules typically exist as rings that together form a chain, like the pattern seen on the front cover of the iconic Book of Kells.
Led by Professor of Chemistry at Trinity, Thorfinnur Gunnlaugsson, the work was carried out by PhD student, Dr Christophe Lincheneau, who is now a postdoctoral fellow at CEA Grenoble. Dr Lincheneau used a metal ‘lanthanide’ ion called Europium and a catalyst developed by the Nobel Laureate, Professor Robert Grubbs of Caltech, to interlock three molecules through a single point. The important discovery was recently published in the high-impact journal of the Royal Society of Chemistry, Chemical Communications. It was also featured in Nature Chemistry’s April issue as one of three Research Highlights.
Professor Gunnlaugsson said: “This work opens up a new avenue for developing complex supramolecular self-assembly structures. The luminescent properties of the lanthanide were very important to our study, as they allowed us to monitor the self-assembly processes between Europium and the molecules in real-time.”
Europium luminescence is a powerful tool with wider applications. For example, it is currently being used to aid authorities in the prevention of counterfeiting, while luminescent lanthanide ion complexes are employed in the various denominations of Euro notes as red and green-emitting dyes.
Professor Gunnlaugsson’s research group, which is located in the Trinity Biomedical Sciences Institute, was also able to accurately determine the mass of their interlocked ‘catenane’ by using the School of Chemistry’s state-of-the-art nuclear magnetic resonance (NMR) spectroscope and mass spectrometry facilities, which are part-funded under the HEA PRTLI Programmes. Their published research was funded by Science Foundation Ireland under the 2010 Principle Investigation Programme.
“We are now actively pursuing the development of other interlocked molecules and self-assembly structures using the lanthanide template design strategy we have developed and discussed in our recent publication. We hope this is just the first of many exciting and important discoveries,” added Professor Gunnlaugsson.
Prof Thorfinnur (Thorri) Gunnlaugsson, a principal investigator at Trinity Biomedical Sciences Institute, co-authored a study about the findings in ACS Nano.
Ronan Daly and Oxana Kotova were also authors of this publication, which explored the phenomenon of single-crystal halide salt wire growth at the surface of porous supramolecular materials.