New Paper on Dalton Transactions!

Many congratulations to Hannah, Amy and Chris ( on their paper that has been accepted for publication in Dalton Transactions, entitled: “Exploring the reversible host–guest chemistry of a crystalline octanuclear Ag(I) metallosupramolecular macrocycle formed from a simple pyrazinylpyridine ligand”. This exciting work was developed by Hannah and Chris in collaboration with Brendan Twamley, Kevin Byrne and Wolfgang Schmitt (Dalton Trans. DOI:10.1039/c8dt04583f). This highly novel work focusses on the use of some 2-(2′-pyrazinyl)pyridine based building blocks, that we have been developing in the TG laboratory and their coordination chemistry with Cu(II) and Ag(I) ions. This has lead to the discovery of metallosupramolecular architectures that have some surprising complexity; some of these systems (the metallosupramolecular macrocycles) being employed in this Dalton contribution for carrying out solvent exchange in a single-crystal-to-single-crystal transformation as demonstrated in the figure below.

Crystal to Crystal Hannah Dalton Trans

Well done and special congratulations for Hannah for her first “Dalton on Dalton” paper!